Science
Related: About this forumDistribution & Type of Marine Debris Polymers on Hawaiian Island Beaches, Sea Surface, and Seafloor.
The paper I'll discuss in this post is this one: Marine Debris Polymers on Main Hawaiian Island Beaches, Sea Surface, and Seafloor (Jennifer M. Lynch et al. Environ. Sci. Technol. 2019, 53, 21, 12218-12226).
As bird populations fall, accelerated by the wondrous goal of converting all of our continental shelves into industrial parks for wind farms, as well as because of the topic of this post, plastic, a part of the phosphorous cycle will be disrupted, specifically the sea to land portion. Many of the world's mined sources of phosphorous are actually bird droppings on Islands. For a short while, the island nation of Nauru in the Pacific Ocean had the world's highest per capita wealth in the world because it exported bird shit, phosphorous, deposited by sea birds over centuries. (The Nauruan Government "invested" all of this wealth in stocks and bonds which collapsed, and now the nation is one of the world's poorest, the bird shit is depleted, and the Island makes its living by imprisoning refugees deported from Australia.) The importance of birds to the phosphorus cycle is described in the interesting book Why Birds Matter, CAGAN H. SEKERCIOGLU, DANIEL G. WENNY, AND CHRISTOPHER J. WHELAN, Eds., University of Chicago Press, 2016, pp 274-275, 279-282.
I mention this, because I often think about the recovery of important elements and compounds from seawater by raising it to supercritical temperatures. This would serve to recover both phosphorous and carbon dioxide in cases where the seawater is dead from deoxygenation owing to agricultural run-off, as in the Mississippi River Delta, the ecosystem of which has been destroyed by runoff to make "renewable" corn ethanol. The eutrophication process which killed it, involves the explosive growth of micro-organisms which sink to the bottom of the sea as they die after getting killed off by the thickness of the mats they form which restricts sun light, are rotted by oxygen depleting bacteria, killing everything else, fish, crustaceans, and other species.
When I muse on this subject of supercritical water oxidation (SCWO) to recover phosphorous and carbon dioxide, I often reflect that a side product of the process would be to destroy microplastics, which are contaminating the ocean in ever larger amounts, and as another side product would be fresh water, since at supercritical temperatures and pressures, seawater separates into two separate supercritical phases, one containing salts, and one free of salts.
Future generations may need to do these sorts of things, because we have screwed them.
(I may discuss a few interesting papers I came across on polymer reprocessing engineering I just came across that were published in the last few days; not processes I necessarily endorse, but interesting engineering nonetheless, in future posts here.)
One thing I had not considered in my musings is the density of plastics, which is a topic covered in the paper under discussion.
From the paper's introduction:
Since Hawaii accumulates debris from a variety of sources, understanding the chemical composition of plastic marine debris is necessary.(15) Seven standardized resin codes are assigned to the most commonly produced polymers: (16) polyethylene terephthalate (PET, #1), high-density polyethylene (HDPE, #2), polyvinyl chloride (PVC, #3), low-density polyethylene [LDPE, #4, which includes linear low-density polyethylene (LLDPE)], polypropylene (PP, #5), polystyrene (PS, #6), and other polymers (#7). Some consumer goods are stamped with their resin code, but weathered fragments are often missing these stamps, requiring chemical analyses for identification.
Polymer identification of plastic marine debris is crucial for understanding sources, fate, transport, and effects in the environment. Because different polymers have various chemical structures, their physical, chemical, and biological interactions within the environment will differ. Sorption rates and concentrations of organic and heavy metal pollutants vary among polymers, making certain polymers a greater threat of contaminant exposure to organisms.(17) Chemical reactions during environmental degradation processes can lead to various polymeric degradation products that have not been widely studied.(18−23) The release of additives, fillers, and greenhouse gases(21,24) are highly variable among polymer type and in some cases even toxic.(25,26) Polymer identification tools also provide indicators of the extent of the debris weathering, a sign of aging or possibly a time estimate since littering.(20,27) Each polymer has a different chemical density, which is hypothesized to be a major (but not the only) influence in vertical stratification and fate of plastic debris in the ocean (Table 1).(28,29) For instance, polymers less dense than seawater (e.g., PE and PP) float and are commonly found at the sea surface,(30−34) while denser polymers predominantly sink to the seafloor.(29,35,36) In addition, polymer identification can confirm that debris samples are in fact plastic and other material is not visually mistaken as plastic.(37) These reasons, plus the need to understand which polymers may affect different marine habitats, provided justification for the present study.
The authors collected plastic samples from seawater, from the beaches, and the benthic zones of the Hawaiian islands.
They were collected by divers, by collecting plastics in trawlers, and by picking them up the beaches. The types of plastics were determined simply, by FTIR, using a Perkin Elmer library. (An alternative, and possibly superior approach to polymer identification is differential scanning calorimetry, DSC, but FTIR is pretty good.
Here's a description of the handling of the samples and the samples themselves:
...um...delicious...
A little more on polymer ID:
Anyway, here is the table, from the paper, detailing the density of various plastics.
Here is a map of the sampling site beaches:
The caption:
(The authors studied the effect of land development on beach plastic accumulation (see the excerpt below).
Debris amounts are higher in the MHI than many other places. Ribic et al.10 reported that Oahu has higher debris loads than the US Pacific coast. MHI beaches sampled in the current study were more plastic polluted than South Korean beaches (means = 13.2 items/m2 and 1.5 g/m2 of 0.5−2.5 cm each)53 even though they sampled additional particles in smaller size classes (<1 cm), which inflates their abundances compared to the current study. The current results are also 2 orders of magnitude greater than the North Atlantic Azores (0.62 pieces/m2 of >2 cm) of a similar size range.54 It is challenging to compare the present data with published debris abundances on beaches because of the differences in particle sizes targeted. This emphasizes the need to report multiple measurements (piece counts, size distributions, and mass) to understand the type of debris in a region...
The abundance of debris:
The caption:
Where the plastic ends up by form:
The caption:
The degree of weathering (probably somewhat subjective).
The caption:
Figure 4. Weathering rank of MHI plastic marine debris across compartments, percentages of pieces. Debris on the seafloor and leeward beaches (A) are less weathered than windward beaches and the sea surface (B) (MRPP, p < 0.0001). Values are mean ± one SD.
Composition by area of collection:
The caption:
Polymer composition as a function of the type of debris.
The caption:
The relationship between land use and polymer concentration is an interesting discussion:
These correlations could be confounded by beach cleanups, but we believe that this possible confounder is a minor variable. Cleanup effort is undoubtedly higher on tourist beaches, such as Waikiki, but large-scale cleanup events are scheduled frequently for the less developed beaches. The exact timing of cleanup effort before our sampling was often unknown. Kahuku on windward Oahu has less land development, is located within the James Campbell National Wildlife Refuge, and received the largest debris amounts of all sampling sites.14 Portions of Kahuku are cleaned up approximately weekly to monthly. It was obvious that a recent cleanup had occurred at one of our three Kahuku transects. Still, Kahuku had the highest debris abundance, suggesting that recent cleanup had little impact on our overall findings.
Percent land development and weathering intensity showed a strong negative correlation (Figure S10B, Pearson R2 = 0.600, p = 0.0051). Waikiki, the most developed, had the least weathered debris, suggesting that the small abundance of debris on this beach is from local sources with minimal exposure to environmental conditions. The least developed beaches (Kamilo, Lanai, and Molokai) had the most weathered debris. Weathering intensity for pieces exposed to sunlight could reflect environmental exposure time. The more weathered pieces on the sea surface and windward beaches were in the environment longer, arriving to Hawaii via wind and ocean currents from distant sources, compared to more recently littered debris on leeward beaches.
Types of debris were correlated with land development (Figure S10C). More fragments were found on less developed beaches (Pearson R2 = 0.362, p = 0.050), while more sheets were found on more developed beaches (Pearson R2 = 0.443, p = 0.025). Fragments are formed from mechanical and chemical weathering after extended environmental exposure. As such, the less developed windward beaches received debris dominated by fragments that were presumably washed ashore from older litter of distant sources...
There is quite a bit in the full paper, and, in any case, it certainly is sobering to contemplate this mess we're leaving for future generations.
While supercritical water oxidation may serve to reduce floating polymers it's not clear how to address sunken or buried polymers, and in any case, the industrial infrastructure to do this would need to be massive, and utilize sustainable energy, which does not include the solar and wind industry.
The paper's conclusion:
Scary, but interesting.
Have a nice day tomorrow.