The Wall Street Journal
December 1, 2006
Polonium 210
By PETER D. ZIMMERMAN
December 1, 2006; Page A12
LONDON -- The gruesome death of former KGB Lt. Col. Alexander Litvinenko will make history. Litvinenko is undoubtedly the first person murdered by the administration of an alpha-particle emitting radioactive isotope; that makes him the first known fatality resulting from a radiological assassination. The isotope, polonium 210, is largely unknown to the public. Litvinenko's death was as ghastly as it is possible to imagine. The radioactive material went to his gastrointestinal tract, where it rapidly killed the cells lining his gut. They sloughed off, causing nausea, severe internal bleeding and enormous pain. It was as if his internal organs received a severe sunburn, and peeled. If the dose was high enough, it was a death sentence, no matter what the doctors tried to do. At best they could have tried to make Litvinenko comfortable until the end.
Radiation poisoning was not detected immediately, even though the symptoms were at least consistent with that cause. At a moderately early stage, according to visitors to the bedside, radiation was suspected, and a simple monitor was passed over Litvinenko's body. It failed to register significant radiation. That is not surprising because of the perverse genius of the choice of poison. Alpha rays, emitted from certain very heavy atomic nuclei, are nothing but the nuclei of helium atoms. They pack a lot of energy, but because they are heavy and slow moving, they do not penetrate the way that gamma rays -- the most common radioactive emission -- do. Alphas are stopped in no more than a sheet of paper or a piece of aluminum foil, while gammas of the same energy will go through inches of lead. The alphas from the polonium 210 coursing through Litvinenko's body were stopped by his flesh, his skin and his clothing. There was nothing to be detected from outside.
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When the use of polonium to kill Litvinenko was revealed, most scientists said that preparing the poison required the resources of a government, or at least the use of a nuclear research reactor. The only economical way to make the material is in a reactor where a target is bombarded with neutrons; the resulting tiny amounts of polonium are then carefully separated in a radiochemistry laboratory. The basic techniques date back to Pierre and Marie Curie's 1898 discoveries. But it turns out that polonium 210 is a fairly common industrial isotope, one for which there are few substitutes. The radiation from a Po-210 source is used to ionize air, so that static electricity can be dissipated from textiles being pulled along rollers, from rapidly moving bands of paper, such as newsprint, and from photographic film. Alpha radiation makes it possible to brush off dust from film without having it immediately yanked back by a static charge.
Indeed, the U.S. Nuclear Regulatory Commission does not even require much in the way of licensing or paperwork to buy polonium sources smaller than two curies. Antistatic brushes, when fresh, can contain up to 10% of a lethal dose of Po-210; air ionizers for use in industry can contain up to the limit without coming under serious regulation, but larger and more useful sources are controlled. Such brushes, and somewhat larger ones, remain on the market.
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Mr. Zimmerman, a physicist, is professor of science and security at King's College London, and previously was chief scientist at the Senate Foreign Relations Committee and science adviser at the State Department during the Clinton administration.
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