A threat to next-generation lithium-ion makers such as Watertown, MA-based A123Systems, which is working on a plug-in hybrid storage system for General Motors, and Reno, NV-based Altair Nanotechnologies, a supplier to all-electric vehicle maker Phoenix Motorcars>
The company claims to have developed a superior type of supercapacitor (Ultracapacitors have many advantages over traditional electrochemical batteries -Unlike batteries, "ultracaps" can completely absorb and release a charge at high rates and in a virtually endless cycle with little degradation - but compared with lithium-ion batteries, high-end ultracapacitors on the market today store 25 times less energy per pound - and again but he power burst that ultracaps provide can assist with stop-start acceleration, and the energy is more efficiently recaptured through regenerative braking) using barium titanate coated with aluminum oxide and glass, to achieve a level of capacitance much higher than what is currently available in the market. The company's system claims a specific energy of about 280 watt hours per kilogram, compared with around 120 watt hours per kilogram for lithium-ion and 32 watt hours per kilogram for lead-acid gel batteries. This leads to new possibilities for electric vehicles and other applications, including for the military.
EEStor claims that, using an automated production line and existing power electronics, it will initially build a 15-kilowatt-hour energy-storage system for a small electric car weighing less than 100 pounds, and with a 200-mile driving range. The vehicle, the company says, will be able to recharge in less than 10 minutes.
People are skeptical because of leakage - high-voltage ultracaps have a tendency to self-discharge quickly -meaning, if you leave it parked overnight it will discharge. Also ceramic structures are brittle by nature and the thermal stresses may cause cause microfractures and ultimately failure - even EEStor only claims that its system works to specification in temperatures as low as -20 °C, but the US auto market requires specs down to -40 °C. Altair and A123Systems claim that their lithium-ion cells can operate at -30 °C. It will be an interesting safety test when a vehicle packed with a 3,500-volt energy system crashes.
But it does have on its board Morton Topfer, former vice chairman of Dell and mentor to Michael Dell.
http://patft.uspto.gov/netacgi/nph-Parser?Sect1=PTO1&Sect2=HITOFF&d=PALL&p=1&u=%2Fnetahtml%2FPTO%2Fsrchnum.htm&r=1&f=G&l=50&s1=7033406.PN.&OS=PN/7033406&RS=PN/7033406United States Patent 7,033,406
Weir , et al. April 25, 2006
Electrical-energy-storage unit (EESU) utilizing ceramic and integrated-circuit technologies for replacement of electrochemical batteries
Abstract
An electrical-energy-storage unit (EESU) has as a basis material a high-permittivity composition-modified barium titanate ceramic powder. This powder is double coated with the first coating being aluminum oxide and the second coating calcium magnesium aluminosilicate glass. The components of the EESU are manufactured with the use of classical ceramic fabrication techniques which include screen printing alternating multilayers of nickel electrodes and high-permittivitiy composition-modified barium titanate powder, sintering to a closed-pore porous body, followed by hot-isostatic pressing to a void-free body. The components are configured into a multilayer array with the use of a solder-bump technique as the enabling technology so as to provide a parallel configuration of components that has the capability to store electrical energy in the range of 52 kWh. The total weight of an EESU with this range of electrical energy storage is about 336 pounds. Inventors: Weir; Richard Dean (Cedar Park, TX), Nelson; Carl Walter (Austin, TX)