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wtmusic Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 11:50 AM
Original message
A GM fuel cell vehicle parked at Pep Boys?
Edited on Thu Mar-06-08 12:08 PM by wtmusic
Imagine my surprise when I pulled into Pep Boys the other day and saw an honest-to-goodness GM Equinox FCV parked in the lot:



The store wasn't crowded so I easily located a guy who looked like he might be the owner (OK, the GM polo shirt helped) and got these stats out of him:

Range: 175-200 miles
Fuel: compressed hydrogen (900 bar)
Availability: 2010 earliest; fleets only

Pretty sure he worked at the GM service center a few blocks away, which is the infamous one featured in "Who Killed the Electric Car?" where the last remaining EV-1s were stored. But what would he be buying at Pep Boys? Turns out it wasn't wiper blades or even a proton-exchange membrane, but a large plastic gasoline can.

Hmm...
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Selatius Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 11:54 AM
Response to Original message
1. What a lot of people seem not to understand is hydrogen is not an energy source.
Merely, it acts like a battery, storing potential energy that can be converted to kinetic energy. The real fuel is used whenever you split hydrogen from oxygen. That process requires electricity, usually generated by fossil fuels.
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wtmusic Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 11:58 AM
Response to Reply #1
2. A pretty lousy battery, at that
given its volatility and low energy density.

But you're absolutely right. I would have pinned him down but he was gracious enough to talk to me. And actually I feel sorry for GM employees these days. They're stuck with upper management that is destroying the company.
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OKIsItJustMe Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 12:35 PM
Response to Reply #2
6. Low energy density?
Hydrogen actually has the highest energy density (by mass) of any fuel. The challenge is that hydrogen itself is not very dense under "normal" conditions. So (for example) that plastic gas can would not work well to carry some hydrogen from the station to a stranded car.


Hydrogen has a great advantage over other fuels, in that it is relatively easy for us to produce.

Given a supply of electricity and water, you can generate hydrogen, and actually do it fairly efficiently.
http://en.wikipedia.org/wiki/Electrolysis
http://technologyreview.com/Biztech/16523/

Hydrogen can be produced biologically as well, and (it seems) more efficiently than ethanol can:
http://www.nsf.gov/news/news_summ.jsp?cntn_id=110648
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wtmusic Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 04:43 PM
Response to Reply #6
24. No.
Edited on Thu Mar-06-08 04:50 PM by wtmusic
Liquid hydrogen has 1/4 the energy by volume as gasoline (there is more hydrogen in 1 gallon of gasoline than there is in 1 gallon of liquid hydrogen).

http://en.wikipedia.org/wiki/Energy_density

You GM guys crack me up.
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OKIsItJustMe Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 06:28 PM
Response to Reply #24
30. Yes
Edited on Thu Mar-06-08 06:29 PM by OKIsItJustMe
Read what I wrote:
http://www.democraticunderground.com/discuss/duboard.php?az=show_mesg&forum=115&topic_id=137390&mesg_id=137405
... Hydrogen actually has the highest energy density (by mass) of any fuel. ...


Read what the Wikipedia entry you referenced says:
http://en.wikipedia.org/wiki/Energy_density
... (Hydrogen has a higher energy density per unit mass than does gasoline, but a much lower energy density per unit volume in most applications.) ...


http://hypertextbook.com/facts/2005/MichelleFung.shtml


BTW: What's a "GM guy?"
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wtmusic Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 08:24 PM
Response to Reply #30
32. Volume is the relevant issue
There simply isn't enough room for hydrogen, in a passenger car, to provide adequate range and/or power.
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kestrel91316 Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 11:59 AM
Response to Reply #1
3. Gasoline is also not an energy "source". It is merely a storage
Edited on Thu Mar-06-08 12:00 PM by kestrel91316
medium for solar energy that arrived on Planet Earth millions of years ago.

You're gonna have to find a better complaint against hydrogen........

Energy can be neither created nor destroyed. All matter is mere energy storage.
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wtmusic Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 12:06 PM
Response to Reply #3
4. Yes, but here's the difference:
Edited on Thu Mar-06-08 12:06 PM by wtmusic
The energy stored in gasoline is returning CO2 to the air which was sequestered while millions of species of plant/animal life evolved...we're now liberating that CO2, warming the planet, and rendering those species extinct.

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OKIsItJustMe Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 12:43 PM
Response to Reply #4
8. An excellent argument for the superiority of hydrogen!
Here's another difference.

We can't "make" gasoline nearly as easily as we can "make" hydrogen.
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wtmusic Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 04:49 PM
Response to Reply #8
26. Both are bad news.
We don't need to make either. Let's generate eletricity from LNG and use it to power electric cars, which don't require new infrastructure, expensive repairs, and generate a fraction of the CO2.
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OKIsItJustMe Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 06:10 PM
Response to Reply #26
28. I don't understand your point here
Edited on Thu Mar-06-08 06:12 PM by OKIsItJustMe
Using LNG to generate electricity to run electric cars would create less CO2 than is being created today. Of course, LNG is in limited supply, and we don't have a fleet of electric cars.

I'd love to see a fleet of electric cars, but that won't happen for several years.

We have a fleet of internal combustion engine (ICE) powered cars, which can be converted relatively easily to run on hydrogen instead of (or in addition to) gasoline.

It would take a significant investment to do the conversion; but it's a lot less expensive than buying a new electric car (even if they were available in the quantities required, which they aren't) or converting a current ICE car to be an EV.

As you point out, the same infrastructure could be used.
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wtmusic Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 08:29 PM
Response to Reply #28
33. Electric cars aren't available because GM doesn't want them to be.
If you haven't seen "Who Killed the Electric Car?" you need to.

We have a fleet of internal combustion engine (ICE) powered cars, which can be converted relatively easily to run on hydrogen instead of (or in addition to) gasoline.

Converted relatively easily? FCVs cost about a million dollars, aren't durable, and have no place to fill up. A minimal (10,000 stations) hydrogen infrastructure will cost half a trillion dollars. Who's gonna pay for it?

Viable electric cars have been ready for 7 years now. They require almost no service and no gasoline. That's why they aren't available.
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kestrel91316 Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 02:10 PM
Response to Reply #4
13. Preaching to the converted here........I know the evils of CO2, lol.
We should be eagerly switching to hydrogen and any other compact energy storage media which can be utilized without doing as much harm as burning fossil fuels does. Which is why I truly don't "get" the beef with hydrogen.

Can't hydrogen be produced with electricity from SOLAR power, lol???
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wtmusic Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 04:55 PM
Response to Reply #13
27. Hydrogen is anything but compact
Edited on Thu Mar-06-08 05:00 PM by wtmusic
There are two huge tanks under the Equinox which run the length of the car, pressurized to 900 bar (if one explodes, think IED). With both tanks full the car can go 200 miles max.

Just making hydrogen requires fossil fuels, unless you use renewables to create electricity and electrolyze water that way.

Or, you can just lose the messy hydrogen step (which reduces it's efficiency by roughly 50%) and transmit that energy through the grid to clean, efficient electric cars.
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OKIsItJustMe Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 06:14 PM
Response to Reply #27
29. There are better ways to store hydrogen
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wtmusic Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 08:36 PM
Response to Reply #29
34. Better?
"Issues with complex metal hydrides include low hydrogen capacity".

"For this system, the following reversible displacive reaction takes place at 285°C and 1 atm...In this reaction, 6.5 wt.% hydrogen can be reversibly stored, with potential for 10 wt.%"

Low hydrogen capacity? 285°C? Explain to me how that's going to work. :eyes:
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phantom power Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 12:17 PM
Response to Reply #3
5. Here's my complaint against hydrogen:
1) it's a very small molecule, and you need special hardware to handle it.

2) it's a very reactive molecule. that's another reason you need special hardware to handle it.

3) it's energy density per unit mass is high, but it's energy density per unit volume is low. to compensate, it has to be stored at high pressure. Yet again, this requires special hardware, and it's hard to keep the weight and size down for an application like an automobile.

There is no reason we need to solve these problems. If you can manufacture H2, you can manufacture methane. Or DME. Or butane. Or propane. All of those are easier to handle, with standard hardware, and they don't require storage at extremely high pressure to work well in an automobile.
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OKIsItJustMe Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 12:40 PM
Response to Reply #5
7. Actually, hydrogen doesn't need to be stored at high pressure
http://www1.eere.energy.gov/hydrogenandfuelcells/storage/metal_hydrides.html

Watch part 1:
http://www.pbs.org/saf/1506/video/watchonline.htm


Metal hydrides are a much safer way to store (relatively) large amounts of hydrogen.
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TreasonousBastard Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 12:59 PM
Response to Reply #7
9. Back in the 80s Mercedes built a bus with...
hydride hydrogen storage. 'Twas a Scientific American about it back then.

Its primary power was a hydrogen turbine but it had a huge flywheel to absorb braking energy and assist acceleration. Lots of other neat stuff in it, and storing the hydrogen at low pressure created heat, which was later used to release the stored hydrogen when needed.

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phantom power Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 01:01 PM
Response to Reply #7
10. Yeah, but why?
What's the payoff over just using NG, propane and friends?
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OKIsItJustMe Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 01:13 PM
Response to Reply #10
11. Because hydrogen is really, really easy to generate renewably
The same cannot be said for NG, propane and friends.
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phantom power Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 01:51 PM
Response to Reply #11
12. Use the H2 as feedstock for making methane (et. al.)
Don't waste effort figuring out ways to get H2 from the factory, through a distribution system, into an automobile. It's just not a problem that needs solving.
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OKIsItJustMe Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 02:15 PM
Response to Reply #12
15. No need to distribute to cars
Anywhere you have electricity and water (say... that little gas station on the corner) you can generate hydrogen.
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OKIsItJustMe Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 02:43 PM
Response to Reply #12
18. Methane etc. may have their uses
Edited on Thu Mar-06-08 02:50 PM by OKIsItJustMe
For example, as an interim replacement for the "natural gas" currently used in stoves, furnaces etc.

However, burning it will inevitably produce COx, which is one of the things we're trying to avoid doing.
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NickB79 Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 03:01 PM
Response to Reply #18
20. If you use atmospheric CO2 to react with H2, the result would be carbon-neutral
When the methane is then burned.

Of course, at this point we need to become carbon-negative to stand a chance in hell of surviving, so just being carbon-neutral probably isn't enough.
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wtmusic Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 04:44 PM
Response to Reply #7
25. Even lower energy density
We're going backward here.
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kestrel91316 Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 02:11 PM
Response to Reply #5
14. Methane "manufacture" is easy: feed kestrel beans.
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OKIsItJustMe Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 02:25 PM
Response to Reply #14
16. That won't work at an industrial level
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kestrel91316 Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 02:42 PM
Response to Reply #16
17. Some days it sure would........
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NickB79 Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 03:03 PM
Response to Reply #17
21. Maybe add some hard-boiled eggs for "high-octane" gas
Or maybe that's just my particular curse.
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kestrel91316 Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 03:56 PM
Response to Reply #21
22. Cabbage, my friend. Cabbage.
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phantom power Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 04:03 PM
Response to Reply #22
23. I once thought I was actually dying. It turned out to be teh cabbage.
I had no idea gas could hurt so much.
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tinrobot Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 02:58 PM
Response to Reply #1
19. True, but is it easier to charge a battery or fill a tank?
That may be the overriding factor as to whether hydrogen wins out over batteries.

Both are similar in that they are storage mediums for electrical energy, but how that energy is stored and transported is very different.
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NickB79 Donating Member (1000+ posts) Send PM | Profile | Ignore Fri Mar-07-08 02:05 PM
Response to Reply #19
36. The fork-lifts we use at work simply swap out batteries
A huge lead-acid pack slides in and out in under 5 minutes with a special grappler.

I could see something similar in a battery-powered car: every time you stop to recharge, you just replace the battery and go.
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wtmusic Donating Member (1000+ posts) Send PM | Profile | Ignore Fri Mar-07-08 05:31 PM
Response to Reply #36
37. Interesting.
Standard battery pack. Kinda like swapping out a LNG barbecue canister.

And when Li-Ion packs are available you wouldn't even need the grappler.
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tinrobot Donating Member (1000+ posts) Send PM | Profile | Ignore Fri Mar-07-08 11:14 PM
Response to Reply #37
38. But with each battery pack worth thousands of dollars...
...it would be a very enticing target for thieves.

I'd imagine security concerns could make a battery swap less than trivial.

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ejbrush Donating Member (186 posts) Send PM | Profile | Ignore Thu Mar-06-08 07:03 PM
Response to Original message
31. 900 bar?!?
Holy crap, that's around 13,000 psi. I truely want a renewable future, but I don't want to be anywhere around that bastard in the event of an accident or fire. WOW!
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wtmusic Donating Member (1000+ posts) Send PM | Profile | Ignore Thu Mar-06-08 08:37 PM
Response to Reply #31
35. No kidding. Ka-boom. nt
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