|
Edited on Sat Nov-27-04 11:07 AM by LARED
Cortlandt Street sample. The Cortlandt Street sample was mainly composed of construction debris , quartz grains, low-temperature combustion material (including charred woody fragments), and glass shards. Chrysotile asbestos fibers were estimated to comprise < 1% of the sample by volume, and much of the chrysotile adhered to carbonate binder. Some skin cells and dyed cotton fibers were present (5,21–23). The findings of skin cells was consistent with the types of particles usually found in dust in the indoor environment. Approximately 35% of the volume of the sample was in the form of loosely consolidated clumps of fibrous lint, of which the greatest portion was glass fibers. An example of the typical form of the glass fibers is shown in Figure 4. In many cases the width was . 1 µm (to > 10 µm), and the length ranged from 5 to 100 µm. The fiber shown in Figure 4 is not a "clean" glass fiber; other materials are agglomerated along the rod. This is typical of features noted for many different types of particles in each sample. The SEM analysis of the fraction < 75 µm in diameter revealed many glass fibers and cement particles, some in a fibrous form containing calcium, silicon, and sulfur, and some particles were composed of calcium carbonate (Figure 5). Chrysotile asbestos fibers, identified by transmission electron microscopy (TEM), were found in the < 75-µm fraction. None of the analyzed particles contained lead, chromium, cadmium, or mercury, although chromium and cadmium were quantified in this sample by ICP/MS analyses.
Cherry Avenue sample. The Cherry Avenue sample is mainly composed of construction debris (including cement, vermiculite, plaster, synthetic foam, glass fragments, mineral wool fibers, paint particles, glass fibers, metals, calcite grains, and paper fragments), quartz grains, low-temperature combustion material (including charred woody fragments), and metal flakes. We estimated that chrysotile asbestos fibers comprised < 1% of the sample by volume. Much of the chrysotile asbestos had carbonate binder adhered to it. We observed some hair fibers and tarry fragments in the sample. Approximately 10% of the volume of the sample was in the form of loosely consolidated clumps of fibrous lint, of which the greatest portion was glass fibers. The SEM analysis of the fraction < 75 µm in diameter revealed many glass fibers and cement particles, some in a fibrous form, containing calcium, silicon, and sulfur.
We used SEM and TEM to examine chrysotile asbestos fibers, lead paint fragments, iron–chromium particles, and soot particles found in the < 75-µm fraction. The soot particles were in the submicron size range (Figure 6). No particles containing cadmium (detected by ICP/MS) or mercury were found at less than minimum detection limits in the 1,000 particles analyzed from this sample.
Market Street sample. The Market Street sample was also composed of construction debris (including vermiculite, plaster, synthetic foam, glass fragments, paint particles, mineral wool fibers, glass fibers, calcite grains, and paper fragments), quartz grains, low-temperature combustion material (including charred woody fragments), and metal flakes. Chrysotile asbestos fibers made up < 1% of the sample by volume, and much of the chrysotile adhered to carbonate binder. This result is different from the bulk mass results, which indicated 3.0% asbestos; this indicates that the sample was not homogeneous. Some dyed cotton fibers, tarry fragments, pollen grains, and metal flakes were also present. Approximately 10% of the volume of the sample was in the form of loosely consolidated clumps of fibrous lint, of which the greatest portion was glass fibers. The SEM analysis of the fraction < 75 µm in diameter revealed many glass fibers and cement particles, some in a fibrous form containing calcium, silicon, and sulfur.
|