The high waters of the Allegheny River flow along the 10th Street Bypass last week. Public water suppliers in Pittsburgh and elsewhere in the region are concerned about higher levels of bromide in rivers and streams as natural gas drilling increases
Unlike radiation, which so far has shown up at scary levels only in Marcellus Shale hydraulic fracturing wastewater sampling done at wellheads, the spike in salty bromides in Western Pennsylvania's rivers and creeks has already put some public water suppliers into violation of federal safe drinking water standards.
Others, like the Pittsburgh Water and Sewer Authority, haven't exceeded those limits but have been pushed up against them. Some have had to change the way they treat water.
Bromide is a salty substance commonly found in seawater. It was once used in sedatives and headache remedies like Bromo-Seltzer until it was withdrawn because of concerns about toxicity. When it shows up at elevated levels in freshwater, it is due to human activities. The problem isn't so much the bromide in the river but what happens when that river water is treated to become drinking water.
Bromide facilitates formation of brominated trihalomethanes, also known as THMs, when it is exposed to disinfectant processes in water treatment plants. THMs are volatile organic liquid compounds.
Studies show a link between ingestion of and exposure to THMs and several types of cancer and birth defects.
"Our biggest concerns are about bromide, which has become a problem over the last six months or so," said Stanley States, water quality manager with the Pittsburgh Water and Sewer Authority, which draws water from the Allegheny River for its 400,000 customers. "Trihalomethanes are strictly regulated because of the health risks. We've seen levels that are threatening the standards."
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