Environment & Energy
Related: About this forumImpregnating magnesium carbonate with polyethyleneimine to capture carbon dioxide.
The paper I'll discuss in this thread is this one: Impregnation of PEI in Novel Porous MgCO3 for Carbon Dioxide Capture from Flue Gas (Xiao et al, Ind. Eng. Chem. Res., 2019, 58 (12), pp 49794987)
Despite the title of the paper I am discussing herein, I personally believe that the concept of the "flue" should be phased out as rapidly as possible. "Flues" are waste dumping devices; in almost every case, they are the equivalent of pipes dumping raw sewage into rivers and other bodies of water. Flues dump waste into what has become humanity's favorite waste dump, it's planetary atmosphere, which is rapidly being destroyed by indifference and/or the inexplicable popular enthusiasm for technologies which don't work very well; here, as usual, I'm referring to the multi-trillion dollar investment in wind and solar energy which has done nothing, absolutely nothing, to arrest the acceleration of climate change. We are now at around 412 ppm of CO2 in the atmosphere; at the end of March, 1998, we were at 369 ppm.
Elon Musk. Tesla electric car. Megawatts Solar. Megawatt wind.
We are oblivious.
As we are oblivious, it will fall to future generations, from the immediate through the end of human time, to clean up our mess, and do so after we have robbed them of important resources. The clean up of the mess we've made of the planetary atmosphere, is an unimaginable engineering challenge which will require the generation of vast amounts of energy while using zero fossil fuels, almost all of which will have been oxidized and dumped in the atmosphere as even more waste to clean up.
After much study, I consider that this task is just over the line of feasibility; it might be accomplished, but only with a massive concerted effort of all of humanity, such a concerted effort being the most improbable feature of the effort among all features, included the technical features.. We are making 1930's fascism look like small change, given the consequences of the environmental results of present day fascism (albeit disguised as "democracy." )
While I oppose flues, I do consider that combustion ironically represents a part of the path to removing carbon dioxide waste from the atmosphere, at least in the case where the carbon dioxide is generated in an atmosphere of pure oxygen (this generated by nuclear heat) with the combustion of waste biomass. Under these circumstances a pure stream of carbon oxides (monoxide and dioxide) are generated; where steam is present, hydrogen and carbon dioxide, a form of "syn gas" that can essentially replace all materials now obtained from dangerous petroleum, can be generated.) Similarly, "dry reforming" heating biomass to high temperatures under an atmosphere of pure carbon dioxide, can generate carbon monoxide, which can be disproportionated into various allotropes of carbon and more carbon dioxide.
For various reasons, including the increase of energy efficiency under certain rather obscure but real circumstances, carbon capture technologies are of interest, even if the idea of "carbon sequestration" in waste dumps is a Quixotic and useless exercise that will not work. Hence my interest in this paper.
My comments aside, the paper begins with a genuflection to the idea of "carbon capture & storage" "CCS" as opposed to what I believe to be essential in order to give these processes any remote chance of being useful, sustainable and economic, "carbon capture and utilization" "CCU." It also refers, as it comes from a Chinese institution, to coal, a fuel I oppose along with the allegedly "green" dangerous fossil fuel, dangerous natural gas, and of course, petroleum.
From the introduction:
Many of the well known examples of solid phased carbon dioxide capture agents are challenging to synthesize on an industrial scale, a point the authors make referring to silica base absorbents, including the well known MCM-41:
What the authors propose is to synthesize a mesoporous form of magnesium carbonate, having the interesting property that its preparation is a case of CCU, inasmuch as the synthesis utilizes carbon dioxide as a reactant:
Methanol is readily available from syn gas. Table 1 lists synthesis conditions. M4, which is the most discussed porous MgCO3 form is prepared with the methanol containing 33% toluene, toluene being a product of the dangerous petroleum industry which is, albeit not industrially, conceivable to obtain from certain forms of biomass, for example by the reaction of butadiene (from cellulose derived furan) or pentadiene (from methyl furan) with ethylene (from syn gas) or propylene (also from syn gas). M4 is prepared by stirring MgO in this solvent under a CO2 atmosphere for 4 days at room temperature.
Further aspects of the process are described, using ethanol, also available from syn gas, and, of course, albeit as questionably as is the case with other so called "renewable energy" schemes, from grain:
The "x" in "xPM" carries through the paper, for example 20P-M, is 20% PEI and 80% MgCO3.
Beginning with Figure 1, let's now just look at the pictures, a useful way to get a feel for a full paper before reading it in detail.
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The testing apparatus for measuring its performance as an absorbent:
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Note that the authors are imagining this material to capture carbon dioxide from the flue gas from the combustion of dangerous coal. In contracts to the combustion of biomass in a pure oxygen atmosphere, the air fueled combustion of coal will contain considerable amounts of nitrogen. Hence the effect of nitrogen is considered important by the authors:
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It seems that the PEI loadings have a fairly large effect on gas availability in the pores, related to the extent to which pores in the magnesium carbonate are obstructed by the polymer.
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"Breakthrough" below refers to the point at which CO2 is detected after the flow has passed over the absorbent.
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20P-M can capture carbon dioxide at fairly high temperatures:
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capacities of M4 and adsorbents with different PEI loadings.
The effect of trace gases on the absorption:
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It is important to note here that even in pure oxygen, combusted biomass will contain limited amounts of these impurities because biomass will contain nitrogen (in proteins and nucleic acids) and sulfur, (from the amino acids cysteine and methionine, and molecules for which they are biological precursors.
The material shows excellent recyclability when the carbon dioxide is removed at approximately 100 C.
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An excerpt from the conclusion of the paper:
Whether we know it or not, whether we spend our time obliviously picking lint out of our navels glibly waxing enthusiastic for Elon Musk's stupid car and/or the endless series of "renewable energy breakthroughs" decade after decade, this while these "breakthroughs" fail to even slow the rise in the use of dangerous fossil fuels and the contamination of the atmosphere, or whether we recognize the need to change our attitudes and face the true magnitude of the problem, we are in very, very, very bad shape with respect to the environment on which all life depends.
Papers like this one allow, nevertheless, for a sliver of hope.
I trust you're having a pleasant Sunday afternoon.